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Vitamin B5 (Pantothenic Acid)

Vitamins

Overview

  • Pantothenic acid, commonly called vitamin B5, is a water-soluble B-vitamin.
  • It serves as a precursor for coenzyme A (CoA) and the synthesis of acyl-carrier protein.
  • Its primary purpose is to facilitate the enzymatic conversion of carbohydrates, fats, and proteins into usable energy.
  • It supports the synthesis of fatty acids, cholesterol, and steroid hormones.

Chemistry

  • Pantothenic acid (IUPAC: (2R)-2,4‑dihydroxy‑3‑[(3‑hydroxy‑4‑methyl‑2‑oxopentyl)amino]‑4‑oxobutanoic acid) has the molecular formula C₉H₁₇NO₅, a molecular weight of 219.24 g/mol.
  • The molecule consists of a β-hydroxy-acid moiety linked via an amide bond to a pantoic acid backbone (a 2-hydroxy-3-methyl-butanoic acid) and a terminal β-hydroxy-acid side chain.
  • It contains two hydroxyl groups, a carboxylate, and an amide, conferring high water solubility (≈ 30 g/L at 25 °C).
  • Pantothenate salts (e.g., calcium or sodium pantothenate) are the common pharmaceutical forms, improving stability and bioavailability.
  • The molecule is chiral; the biologically active is the (R)-enantiomer.

Sources & Quality

  • Naturally, pantothenic acid is abundant in animal liver, kidney, eggs, and dairy, and in plant foods such as mushrooms, avocados, and whole grains.
  • Commercially, it is extracted from fermentation of Corynebacterium or Bacillus species, or chemically synthesized from β-alanine and pantoic acid intermediates.
  • High-purity calcium pantothenate is produced by neutralizing pantothenic acid with calcium carbonate, yielding a stable, water-soluble powder.
  • Quality metrics for supplements include ≥ 99 % purity, absence of heavy metals (≤ 10 ppm lead), and verification of the (R)-enantiomer through chiral chromatography.
  • Good Manufacturing Practice (GMP) certification and third-party testing (e.g., USP, NSF) help ensure consistent potency and safety.

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